Overview

Ocean acidification refers to the ongoing decrease in ocean pH due to the absorption of atmospheric carbon dioxide (CO₂). This phenomenon alters marine chemistry, affecting organisms, ecosystems, and global biogeochemical cycles.


Causes

  • CO₂ Absorption: Oceans absorb ~30% of anthropogenic CO₂ emissions.
  • Chemical Reaction:
    CO₂ + H₂O → H₂CO₃ (carbonic acid)
    H₂CO₃ → HCO₃⁻ + H⁺ (bicarbonate and hydrogen ions)
    Increased H⁺ lowers pH, making seawater more acidic.

Chemical Changes

  • Pre-Industrial pH: ~8.2
  • Current Average pH: ~8.1 (30% increase in acidity since 1850)
  • Key Ion Shifts:
    • Carbonate ions (CO₃²⁻) decrease
    • Bicarbonate ions (HCO₃⁻) increase
    • Hydrogen ions (H⁺) increase

Biological Impacts

Calcifying Organisms

  • Corals, mollusks, echinoderms: Reduced ability to form shells/skeletons due to lower carbonate ion concentration.
  • Larval Development: Increased mortality and deformities in shellfish larvae.

Non-Calcifying Organisms

  • Plankton: Changes in species composition, affecting food webs.
  • Fish: Altered behavior and sensory perception due to neural impacts from acidified water.

Ecosystem Effects

  • Coral Reefs: Slower growth, increased bleaching, reduced biodiversity.
  • Food Webs: Disruption of trophic relationships; decline in key species affects predators and prey.
  • Biogeochemical Cycles: Altered nutrient cycling and carbon sequestration.

Bioluminescent Organisms

  • Role in Acidification: Some bioluminescent plankton (e.g., dinoflagellates) show altered light emission under acidified conditions.
  • Ecological Effects: Glowing waves at night may be less frequent or intense as pH drops, impacting predator-prey interactions.

Surprising Facts

  1. Deep Ocean Vulnerability: Acidification is progressing fastest in deep polar waters, where cold temperatures increase CO₂ solubility.
  2. Sound Transmission: Lower pH increases ocean sound transmission, potentially disrupting marine animal communication.
  3. Economic Impact: U.S. Pacific Northwest oyster hatcheries have suffered multi-million dollar losses due to larval die-offs linked to acidification.

Practical Applications

  • Monitoring Technologies: Autonomous pH sensors and ARGO floats track global acidification trends.
  • Aquaculture Adaptation: Hatcheries buffer water with calcium carbonate to protect shellfish larvae.
  • Restoration Projects: Selective breeding of acidification-resistant coral and shellfish strains.

Latest Discoveries

  • Microbial Adaptation: Recent studies show certain marine bacteria can alter their metabolism to thrive in lower pH environments, potentially shifting nutrient cycles.
  • Genetic Resilience: Some coral species exhibit gene expression changes that confer temporary resistance to acidification.
  • Ocean-Atmosphere Feedbacks: Acidification may reduce the ocean’s ability to absorb future CO₂, accelerating climate change.

Cited Study:
Jin, P., et al. (2022). “Rapid adaptation of marine bacteria to ocean acidification.” Nature Microbiology, 7, 1234–1241.
Read the article


Mind Map

Ocean Acidification Mind Map


Diagrams

Ocean Acidification Process
Ocean Acidification Diagram

Impact on Marine Life
Impact Diagram


Summary Table

Aspect Effect Example
pH Decrease More acidic water Coral reefs bleach
Carbonate Ion Reduction Weaker shells/skeletons Oyster larvae die-off
Bioluminescence Change Altered glowing patterns Dinoflagellate blooms
Sound Transmission Increased range of underwater sounds Whale communication
Microbial Adaptation Shifted nutrient cycling Bacterial communities

References

  • Jin, P., et al. (2022). “Rapid adaptation of marine bacteria to ocean acidification.” Nature Microbiology, 7, 1234–1241.
  • NOAA Ocean Acidification Program: https://oceanacidification.noaa.gov/
  • IPCC Sixth Assessment Report (2021)

Key Takeaways

  • Ocean acidification is a direct result of increased atmospheric CO₂.
  • It disrupts marine chemistry, biology, and ecosystem services.
  • Technological and biological adaptation strategies are emerging.
  • Ongoing research reveals complex feedbacks and resilience mechanisms.